T
I1P
chi
Hila hoc, T. 45 (2), T, 176 -
180,2007
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TONG HQP
VA
CAU TRUC CUA MQT SO PHUC CHAT
TRANS-DICLORO(5AFROL)(AMIN THdM)PLATIN(II)
Dell 1'00 SO(11/ 8-6-2006
NGUYEN
THI
THANH
CHI,
TRAN
THj
DA,
vu
QUANG
NHV,
NGUYEN
HOU
DINH
1'rut'IJlg
Da.
hoc

/H-NMR
spectra studies.
1-
M0
DAU
Platin
cung nhu plurc
chat
cua no
dual'
Ling
dung
lam
xuc
1~1c
rho
nhicu
qua
umh
long
hop
trong
phong
thi
nghiern
va
tmng
cong
nghicp
hoa

voi
phoi
ur
olefin
thicn
nhieu
thi
hau
nhu
can
chua
duoc
nghicn cuu.
Trong
cac
bai
baa
uircc 14, 5 j,
chung
toi da
thOng
baa
djeu
kicn
tong
hap
va xac
dinh
cau
true

qua:
tong
hap.
cau
true,
tinh
chat
ella
mot
so plurc
chat
1I"UIlS-
diclororsafrohtamin
thomjplatintll). Safrol
duoc
viet tat la Sal'.
II - THUC'
N(JllI(,M
1. Tong
hop
cae
phue
-
Tong
hap
po: Pht(c po
dual'
tclng htip
thea
phuong

khoang
5
gio
thu
dual'
kct
iua. Rua ket tua liin hrot
bang
dung
dich
IICI
O,lN,
nuoc va ruou lanh. San
pham
dual'
ket
tinh
lai
trung
hen
hop
nrou-mroc.
2.
Phuong
lien
va
phuoug
phap
ughien
cuu

Tiel'
Khac
trong
he giiti
hap
axcton/axit
nitric = 10: I.
hien
vet
bang
hoi iot. DO dim
dien
phan
tu'
do
tren
may
III
88119
N
cua
My.
I'ho
Raman
ghi
trcn
may
Micro
Raman
LABRAM

vien nen voi
KBr.
Ph"
IIl-NMR
cua
cac
phuc
chat
dual'
do
tren
may
Brucker
ADVANCE
(500
MHz)
tai
Vicn
l
loa
hoc
thuoc
Vien
Khoa
hoc
va
Ccll1g
ngh<;
Yi¢t Nam,
tat