!" #$%&'%()*+$
" ,-!$%(./01)2" #$%&'))2
3" #$%(4." ,5%)6%7%,8!,)49
)%3:;<!%. ));41& =>?)@A
B$%&'" #0%(,C%D<=-<EFGD6
HG6%IJ&',K;41<LM-%*
!<E&GN$%&',GD&OG%%J!
=<741<L," P%3<!,Q0%3&R
6%01, %($(<E&GN$%&'R4 =S
%3 =TRB'O)U#490C& ,GD$%(.,K
-<<H0V) ,C%6%,=G6
W&%E1/,8;#%'<,XO
Y%%" ,KO-K,GD01,
Z
1.
[I,+J" #$%&';= F-*45
&R&R0\ %3 <=Q/!J(
< = Q / \ " # G = @ %(< ] :]<O%
%4%%>): %4%%>J Y%%I,+
;&RGY%^;,GD1 %3 -=GD3
CD< )_%^ 4541<L<I$G
4%M!4%Q!$+J( <F-,-= F" P
CD< `Z!Zabc
2. !"#$% &' (')*+%
d #$%&'" #$K%( ,GD0=$e
(0%( (%6%!)#" #" #
+41& =&R-*45fR ,GD\" #,GDg
• Zeolite và xúc tác chứa zeolite`Z!ZZbc
vO%OD<=J %4%%!=%K-= ',Q0%3
B= 'J',GD,QG0Uhww!8!=H)6%
B=xO%,GD(hg)6%&' %4%%)6%,=
4V%%!%4 ,-,GD&FP0U<G/<<,Q0%3D<&'
.xO%f'.xO%-h+!-,5)%
)\<1%!)#(',GD4FI=8%
2<JxO%O!GY%-K0%K %t.<EF
G4
p
[ y] y &%y y
p S p p
,-!A*J%$%h%[z&Au3%y
p
T]
p
y
S
)A45
<EFG6!N,E&{p
2= h!xO%,GDh\,/)*= '/01%,/)*=
'4%:#ZZ>_( ,/)*5%)6% OQqh-
xO%h%]_( 5%)6% OQbh!-xO%h%f|!-=
'G/@G} x%:#Zp>_GY%,8(h,GDR
h%xO%!',GD,QG0N%$+G6~F4C•$ +I,Q
GJ45h%xO%,GDg<C0%($%&',GD€
N01ZZ
S
p
y
S
q!l%y
p
l!n
p
y kq
[O% _
l
y:]
p
y
S
>
l
:%y
p
>
qa
pq
p
y bkƒka:pnƒok>
v[Ao)ZZ oqob
3.2. Bh#J&'`p!ZpZc
f'$%GY4FINh4
Xúc tác dạng bụiB-$+G6h\ZAla„:<6qaAla„>
Xúc tác dạng vi cầu B-$+G6h\oaAZoa„)6%&'0I%!&'
)% +0*%^!);&'+0*C/
/1
3.5. %4%&'
f'0*=h+" #<1. E+5
h002Qh,J&'#(,K%4%&'!GY%
<1%%(,550U$$+-^%4%i(" 1J"
#,55494%By)By
p
B<1.H%2 %3_%
^<1.$FD<=G e
B … y
p
→
By
p
SSnpkƒSqabn[†T$
B … ZTpy
p
→
By ZabpnƒZaSZq[†T$
By … ZTpy
p
→
By
p
pSboaƒpSkoo[†T$
p
… ZTpy
p
→
_%3GDH,GDg,K=<%3&')^<1.!
%^,GDg,K41& =/%G6g
_%3,%4%<I %2 )=&',GDg^%
4%[.,%4%<1%,GD$5(Q9,K$u,101,
h+J&'^,101)=,2)34%%GY!)#($
-Q$+By
p
$+$-%1/7!" #‡$,K&1
N%3," +%3I0€6%<J&' $%%4%!
GD5^h%&'<1%@%K ,K$%<I5%,,h+
&'
4. )$./'01$ (')*+%
4.1. QGJ %3 `Z!Zpqc
b
_ %3 /01" #$%&'<=E$J
Q $%G=$+" KB'GY.o÷Zam<E,h4%
,(Soa
a
B)-%3,4% 5%6%opa÷oqa
a
B%2 GYD<!GY%
‡-Kg1<E,hMJG=$+" K!<E,h$O4OO
A4%J$%%35)-K1<}%J" #$F
4<x ) 41& = YQ<E,hx J
+$%h%B,QG" =J %3 -1GN" (,*
,(u% J" #$%<<E,h!U45,QG
i!<-0!GD@A4<!GDh<
=%/!G e!$%h%)5
0/,)^:)#" #tGIh5002Q
&'>!4<)h<=._)
k
_ %3 Q.%2 4<)$%h%!$%$%
<1%" &FP0U4h,K;,GD %3 -=GD
" #$%&'
_-%-h%!G6$%,G %3 )" #$%&'!'
<1%%. $‰=GDJ %3 !h%&'g) eO,%2
$%3$‰ ;!%3 " 1J<G/<<4h %3
%3 gGY%" (,*<G/<<4h %3 +D<
%3<$%&'!GY%-K4FI
- %3 4
• _-Z- %3 M-<E,h$O4OOA4;,GD\
" #G=@%(<)-%6%h4%\pZa,(Sba
a
BB'-j
0#\alba,(alSaGD<EF 0#)$1
Zna÷paaE- %3 5=g,K41& =&R)&R
0
• _-p- %3 =\<E,h4%G=E$-
%3,4%\Saa,(oaa
a
B:ooa
a
B>_--,QGj
0#\alla,(anpa!GD<EF 0#\pla,(SSa
• _-S- %3 -<=!)-%6%h4%\pZa÷
oaa
a
p
p
B
q
B
p
q
B
p
b
B
S
b
B
S
l
AB
q
l
%AB
q
l
ŠIJ$+$%&'
• 1<L<<A<<O %3 " #<O)"
#414 ==,02Q
• rE,h$+<<A<<O!0 A0 O %3 41& =$+
Hr! %3 $-,K;= F-*45<)
&R!)$+,5EI! %3 CD<-
5.2. rE,h&R`p!ZZkc
E41<L+J" #$%&'!%3 4 =&RGY
,$1\SaASomGD %3 ,O)$%%3 4 =
)=GD&R<I )=GD %3 !&'!(,
3
• _( %3 -%2 <O#&R ,GD-=GD
• _( %3 -%2 <}%#&R ,GD-*45=<
n
• _( %3 -%2 G e#&R ,GD‡-%2
G e:GY%(ZomCGDG e- %3 >
•1ZSBu% J&R$%&'`Z!Zpbc
pa
q
akp÷akk
GD:mi>
aaZ÷apa
*45‹y_
lk÷no
*45[y_
kl÷lo
<0:m>
0/
B,GDg•y %3
" #5
•1Zq<)+=,QGJ<E,h$O4O−4%
Za
Bu%
rE,h-%3,4%!
a
B
Zno÷pka pka÷Soa Soa÷qpa
{qpa
20
4
d
_%3,,,Q!
a
B
*45&O
*45%!TZaa
0/!m
54!mi
alb÷ano
−qa÷−ba
pa÷So
Za÷pa
alb÷ank
−pa÷−oa
o÷Za
ba÷la
aao÷Za
anb÷ann
%3 )=GDx%M
4%Q-%3,4%{Soa
a
B!-j
pa
q
d
Žaln÷ann
1<L.GD6h<=/GDG e
,-/$1Zo4)6% %3 0, _-,GD4FI
%3 $%%3)5Q%%3 ,5^_
GY%^g- %3 41& =0-
6. 7843'9')
B/(<1.$%&'/(%0%BE+
%0%,GDh$%<EF0J %3 I)6%
E&+J&'
• E&+&'-ph%h%•4O:
…
>)O•%4:>
ZZ
• E•4O$%%<1.-$1R<h,:
…
>^
EO•%4#%( OO-& G6;,%3F
r1.$%&'&1O%%,h4
%%,hZh%0%
p p p Z
: >
n n n n
p…Z p…p
p…Z
p…p p…Z
…B B … B
B …B B … B
B →
→
B%6%h%-K%<1.,<E!$%!
$GI•%(,C%J%0%%(<%t,($%--=
'02)7=!-,02=B-K4s<&(<,02J%0%
O.@4
‘0%0;S{‘0%0;p{%0%0;Z
Zp
02J%0%49" (,*.,%<1.%(<O
J'#%0%0;S-,02=49<V<;%3
4 =D<=%4A<}}%B=GD41<L,GD" (,*0N%
<1.J%0%,Q0%3<1.<E j!,<E)
K)*
7. 8:;')')1 (')*+%
7.1. [., K-B`Z!Zpkc
K-BGD41<L,GDhOY%%GD+
O0%K .
BŽZaaA
mK+GD41<L)6%,%K4% 5%/,%K4% 5%J
&R
%3 uO4@0%(,C%-!P
BŽZaaA:ZaaAx>
xm&R- %3
7.2. 5,h<%3 %`Z!Zplc
%3
• i% R5,
h< %3 %!49
%1, K
- B^$%
%15, h<%3 %#
, K- R
• i%4FI&'-h+
⇒
-KR5,h<%3
⇒
R
R4 =%(0*
• i%R5,h<%3 !( R%3,<1.!49R*45J
&R)R%3 4 =O}%$+
7.3. j3%7GD&'T %3 :fT‹>0%45 &'
`ZZpnc
,C%u3fT‹,C%%3,O!,C%Y%%G J
&'O)^%4%!,C%GD50&'
Zq
#Zq“GNJu3fT‹
Ru3fT‹
⇒
R, K-!R%3 4 =5T %3 !
GGD50&'%1
i%%75,h<%3 [TT[$,C%!( Ru3fT‹
⇒
h
+ 0#&'R
B5!mi
BQ!mi
[=!mi
‹!m
‹
y
!m
‹
!m
qaa bqo lZo qnp ZZb Sk SpS Sp bbl kk poS
qpa kap kbk qnk Zba qo pka pl bZn lo pnb
qSo kpZ kqq qnZ Zlp ql poS pb obo nb SSn
qoa koo bnn qko ppp ol ppq pZ oal Zal Slq
qka kqq bZn Slb pno bo ppo pn Snb ZSn qbo
qlo kqn onk SSp Spb kl pqk pq plb Zoa obq
oaa kSl opo SZS Skp kp pZa Sp plb Zql obq
7.5. “GNJ<4 =`Z!ZSac
R<4 =
⇒
%3 4 =&RR!%3 4 =$+B
Z
AB
S
%1!GD
O}%)0/%1!GD0R
⇒
=
GD&R%1
#Zo@<I J%3 4 =41<L$%)45
[O‘‘),8,G),\ZnopB3•BB,GD1%%(
Zk
U,h%3 4 =)=GD&R/!)6%=GD %3
&= /
8.3. B3•BB
d #•BBJ458
%3<C%%(-
8.3.1. d #J8•yr`Z!ZSSc
d 0G61%%(%I!%
3 •BB J •yr ‡ < I
$%U K-Q Q
d #J•ryr,@/]4
Ay%B<%KB+8•yr,8%(
$(ph%•BB
• h%^%4%,5Z=<
• h%%4%%=<
Zl
#Zb/,‹BB%4%Z=<
J8•yr
8.3.2. d #JiO`Z!ZSSc
@); K&',GD@%3O<G/–,.= ;D%)#
-Kg)Q,K,%2 $%K" # J&'d #
$%,GD@%3^<1.h5,.:^5,.>
35&,GD,QFJ5,.^%4%&')
$$+%(<&'GD%2 i%K ‹•BB,GD#0#Zl
Q,%K+JO)^%< %3 ,GD1%%(UR
GY4@%(<&'%7&') %3 !0<; %,GD,C%
0U\,QN<,Q<8^%4%,KR^!
<C0%(%3< H!-,GD8%3<,
?)@G•yr!iO!O!‘•r!W&&%. ,K%3/
pZ
#ZZad #‹p‹J‘•r#ZZZd #‹•BBJ8W&&
Nguyên
liệu
Chuẩn bị
xử lý
Lò
phản ứng
Sản phẩm
qua chưng tách
Xúc tác đã
làm việc
Xúc tác đã
tái sinh
Lò tái sinh
xúc tác
UI,%,hR4 =%3 " 1=!4FI %3 Q/!%(
$%3,GD&')<1%$%(=
d @(g35$%&'6<4%4FI&'h0I%
)% !GY%=--%2 G ,%K/35$%&'
6<&' K,_7G ,%K,-
B%(0*+J" #%(0*<1.)%(0*%4%,2 -
= h=,/%1!4)6%h%(0*$J" #$%@(
'#w
@ &'\%(0*<1.,(%(0*%4%)GDh%
Y4@); K%IJ/%)$+%6%h
4@$ =h9J&')/% %3 €,(4@,
• ‹OA5,.z
• %4%));I%3J$+$-%z
• rE,h<E%41<Lz
nq _ Ph,
•<;‹OA5,.`Z!Zqkc
_ %3 6%\0K. %3 ,GD" %(0*,C%%3
5 ! %3 6%-K,GD)6%< By:<E,h
QJ" #$%&'>4 ,-" ^,5- %3
$%_ %3 $%,GD%(<&')6%&'-,8%4%N,J
5,.!$%,- %3 0/%g)6%wD<J/%-)&'
,GD,%<+6%,uJ5,.!,Y%&1<1.$%
&' ( %3 ,2 %<1.) K5,.!
^O,GDgG%(0*&')/%0
[0<;,GD%($(,Q0%3!05+N)Q!g/%G6,K
C%&') !G);49h(,(.5%,%3GD" N
h%J&')/%$+,8)%3g5,.)0<;/%J
O,GD%($(" #•BB)6%Y%%%(<&'s%7&')
$%$H%&'!/%41<L-,GD K6%<E,h
f',8)%3,GD" )g/%:^%0<;F&'>
0UC%/%G6)•<;F$u%3)I, C%(
00* 5O)0*=<<I&'^/%h&'
,K'$+) G6$%4^%4%B,%2 u5,/%
pS
+D<%3)IB%(<1%$%KQ9Y%%G J&'
0<;F,K<1%g" %2 $$+^%4%<
4 =O,GD$5(0U0<;,%2 u<4 =J<E
,h
^%4%)$5%;I%3J$-%^`Z!Zqnc
f'-.5:50&'>,GD K" ),%2 $%K)
N<4 =_G6=\,0Ks0<,GD K6%35
&FPG61%B.R$(D<J35<4 =%1GD
41<LM:B
pŒ
>^!RGDB
S…
/%\%(0*N<4 =
,GD K 6% 3 5 $+ % %3 G ,GD &F P! ^ < H
0:&R$C,*> ,GDN,%(0*<4 =6%<
C,*!_<M ,GD\,:o>" 3%)0K.i(
" 1!4 35!;,GD<E,h$+B
Z!
B
p
!41<L-K
,GD g $+ % %3 E 2 rE ,h B
S
!B
q
. %2
<<O)0 O,GDg %3 E 2$)41
<L%(<O&R,8$F0
\<E,h+!^;,GD<E,h41<LG<
Q!By)ByrBy-K h%<!) 5%g
< Q,8,GD4h$H%0g&'[<41<LJ%(0*
0g&',GD g)6%By!<^h%,GD0/" 3
5,C%%3!%)0K. Q
po