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MỤC LỤC

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Bài 1:
Làm quen với chemdraw, xây dựng công thức hóa học dạng 2D và 3D
5

Bài 2:
Thiết kế hệ phản ứng bằng chemdraw
10

Bài 3: Làm việc với cấu trúc………………………… ……… ……… 35
Bài 4:
Làm quen với Hyperchem, xây dựng công thức hóa học dạng 2D và 3D
43
Bài 5:
Khảo sát tính chất quang phổ của họ màu azo
48
Bài 6 64
TÀI LIỆU THAM KHẢO 30

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Bài 1
Làm quen với chemdraw và Xây dựng các công thức hóa học dạng 2D và 3D
Phần 1: Làm quen với chemdraw 9.0 pro.
- Cài đặt bộ phần mềm chemdraw 9.0 pro vào máy tính.
- Khảo sát các thành phần cơ bản của chemdraw 9.0 pro thông qua giao diện của

Tên tiếng Việt Chức năng
chính
Phím tắc Ghi chú
thêm

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Phần 2: Làm quen với cơ sở dữ liệu của chemdraw 9.0 pro.
- Khởi động vào window của chem draw Ultra 9.0
- Dùng menu File, chọn Open để mở thư viện có sẳn:

Hình 3: Giao diện của menu Open trong chemdraw 9.0
- Chọn một thư viện có sẳn như sau:
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Giáo viên biên soạn: Trần Hữu Hải – Khoa CN Hóa 4

Hình 4: Giao diện của menu Look in trong chemdraw 9.0
- Dùng chuột chọn lần lược các thư viện vào click vào màn hình soạn thảo để xem
kết quả cho bộ thư viện Aromatics.
- Sinh viên tiếp tục khảo sát các bộ thư viện khác có sẳn như sau:

Hinh 5: Bộ thư viện có sẳn của chemdraw
Phần 3: Làm quen với cơ sở dữ liệu của chemdraw 9.0 pro và chuyển chúng sang dạng
3D bằng chem 3D Ultra 9.0.
- Dùng chuột chọn lần lược các thư viện vào click vào màn hình soạn thảo để xem

đó vẽ sơ đồ phản ứng cụ thể. Sinh viên tiến hành trong 2 buổi.
Phần 1: Làm quen với các công cụ của chemdraw 9.0 pro để vẽ công thức hóa học
1.1 Tạo một tài liệu của chemdraw.
Sinh viên khởi động vào window của chemdraw vào menu File để tạo một tài liệu mới như
sau:
- Bắt đầu ChemDraw.
- Trình đơn File, chọn new…….document

Hình 10: Giao diện làm việc của chemdraw
- Từ trình đơn file, chọn save as.
- Chọn tên file: hoa hoc 1.cdx. trong hộp file name.
- Lựa chọn một nơi để lưu giữ hồ sơ hoa hoc 1.cdx
- Chọn save
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Hình 11: Cửa sổ save in của phiên làm việc
1.2 Vẽ công thức hóa học đơn giản.
Sinh viên dùng các công cụ trên Toolbar:

Hình 12: Thanh công cụ thiết kế di động của chemdraw
Vẽ công thức hóa học của vòng benzen với màn hình làm việc của file: hoa hoc 1.cdx. Sau đó
save lại ở định dạng sau:
- hoa hoc 1.cdx
- hoa hoc 1.png.
Chuyển công thức mới vẽ xong qua 3D và lưu lại với file name: hoa hoc 3D 1.c3xml, dùng
trình đơn View và dùng lệnh model display mode để thay đổi model display và save cho từng
kiểu.
Sinh viên làm lại các kỹ năng trên với các công thức hóa học sau:

3
H

Kết quả vẽ thu được khi chuyển qua 3D, save lại với tên file là: hoa hoc 2.png

Thiết kế hệ phản ứng sau trong chemdraw và save thành 2 dạng:
- hoa hoc 1.cdx
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Bài thực hành ứng dụng tin học trong hóa học
Giáo viên biên soạn: Trần Hữu Hải – Khoa CN Hóa 10
- hoa hoc 1.png.
OH
NH
2
SO
3
H
HO
3
S
Cl
Cl
Cl
NHOH
HO
3
S SO
3
H
Cl

S
NN
SO
3
H
+
+

Bài báo các được hoàn thành vào cuối buổi thực hành thứ 2 và nộp cho giáo viên ngay tại lớp.

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Bài 3
Working With Structures
(Làm việc với cấu trúc)

Trong bài thực hành này, sinh viên vẽ các công thức hóa học từ đơn giản đến phức tạp và từ
đó tính toán với những cấu trúc này. Cụ thể như sau:
- Kiểm tra một cấu trúc để xác định hóa trị và những lỗi về cấu trúc đã vẽ.
- Xem thông tin phân tích về cấu trúc đã vẽ.
- Trình bày những tính chất hóa học (cho) một cấu trúc.
- Ánh xạ từ Nguyên tử tới Nguyên tử gán.
- Chuyển cấu trúc gán tới hình ảnh và tính toán phổ NMR

Phần 1: xem các thông tin về phân tích cấu trúc (Viewing Analysis Information)
Window phan tích sẽ xuất hiện các thông tin về phân tích cấu trúc như sau:
- the chemical formula.
- exact mass
- molecular weight

Lúc này window se xuất hiện về thông tin phổ
1
H or
13
C NMR như sau: PDF created with pdfFactory Pro trial version www.pdffactory.com
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