PHỤ LỤC
Phụ lục I; Các phổ của chất HM).
Phụ lục II; Các phổ của chất RM2.
Phụ lục III: Hình ảnh cây Mức hoa trắng
PHỤ LỤC I.
• Phổ UV của chất HMi.
• Phổ MS của chất HMi.
• Phổ ‘^C-NMR và ^H-NMR của chất HMj.
• Phổ m ô phỏng ‘H-NMR của chất HMị.
• Phổ mô phỏng ‘^C-NMR của chất HMj.
• PhỔDEPT90&DEPT135củachấtHM ,.
A B S
A B S
A B S
2 . 6 3 3 6 5
3 . 8 2 4 4 9
3 . 5 5 7 3 6
N M
N M
N M
2 9 4 . 0 0 0
2 5 8 . 0 0 0
2 2 7 . 0 0 0
-0.0414
ABS
Basel ilie
93
OFF
SBU
Page
8 May 2007

6 1 . 0 5
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3 9 1 9 7 3 . 0 5
3 2 9 5
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3 3 4
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6 9 6 8
6 3 . 0 5
9 7 4 8
7 4 . 0 5
9 0 9
8 7 . 0 5
1 0 5 9
5 3 . 1 0
1 0 6 1 7
6 4 . 0 5
1 9 1 6 7 7 . 0 5
1 5 2 5
9 1 . 0 5
2 3 3 7
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3 4 8 5
6 5 . 0 5

9 6 . 0 5
8 9 5
5 9 . 1 0
6 7 5
7 0 . 0 5
1 7 0 7 8 3 . 0 5
2 8 4 7
9 7 . 0 5
4 1 9 3
6 0 . 1 0
3 8 0 1
7 1 . 0 5
3 5 8 5
8 4 . 0 5
1 4 1 4
9 8 . 0 5
1 0 4 9
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D - D I P l O O ,
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a b u n d .
m / z
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1 9 9 5 2
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1 5 6 . 0 0
5 0 5
1 1 1 . 0 5
1 3 1 1
1 2 9 . 0 5
1 4 9 3 1 5 7 . 0 0
3 2 3
1 1 2 . 1 5
6 4 0
1 3 5 . 1 5
3 5 2
1 7 1 . 1 0
3 3 6
1 1 3 . 0 5
6 2 8
1 3 7 . 0 5
5 7 3 7 6
1 8 4 . 0 0
3 2 0
1 1 5 . 0 5
5 4 9


1—I

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100 120 l4o 160 180
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1 $ 4
8 0 0 0
6 0 0 0
4 0 0 0
2000
1 3 7
3 1
2 6
3 9
5 3
8 1
'I-
4 0

1 4 9 . 9 5 9
1 4 4 .8 4 6
1 2 1 . 8 4 4
1 2 1 . 6 8 4
1 1 6 . 5 4 0
1 1 5 . 1 1 5
4 0 . 0 0 1
3 9 . 9 2 4
3 9 . 8 3 4
3 9 . 7 5 7
3 9 . 6 6 7
3 9 . 5 8 9
3 9 . 5 0 0
3 9 . 3 3 3
3 9 . 1 6 6
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165 160
■ I ' ' ■ T— - . - ^ 1 , , . , I ■ , ■ . I

|-
155 150 145 140 135 130 125 120
Current
Data Parameters
NAME KINH HMl
EXPNO 2
PROCNO
1
F2 - Acquisition Parameters
Date 20070516
Time 11.19
INSTRUM
av500
PROBHD
5 mm Multinucl
PULPROG zgpg30
TD 65536
SOLVENT
CDC13
NS 256
DS 2
SWH 32679.738 Hz
FIDRES 0.498653 Hz
AQ 1.0027661
sec

PL13
22.00
dB
SF02
500.1320005
MHz
F2 - Processing parameters
SI
32768
SF
125.7578513 MHz
WDW
EM
SSB
0
LB
1.00 Hz
GB
0
PC 1.00
ppm
KINH-HM1-DMS0-C13CPD&DEPT
DEPT90
ìiệmếềimểmmm
'■'1

1'"
200 190
70
60

-T-1-p-r
70
T^JTT
60
n-rp-T
50
■ ■ I • ■
40 30
i-ryrr
20
ppm
KINH-HM1-DMS0-C13CPDSDEPT
DEPT9 O
170 165
160 155
150 145
140 135
130 125 120 115
ppm
DEPT135
CH&CH3
CH2
170
C13CPD
165
160
155 150 145
140 135 130 125 120 115
ppm



1

•

-
^ ^ 1

• ^

-
• \

-

-

-

-
\
-

-
■ ^ 1

■
-
^ • 1


155 150
145
140
135
130
125 120
115
ppm
■
DU=C:/Bruker/XWIN-NMR, USER
Fl=240. OOOppm, F2= -5. OOOppm
,=VH_KINH, NAME=KINH_HM1, EXPN0=2, PR0CN0=1
MI=0.00cm, MAXI=10000.00cm, PC=1.400
#
ADDRESS
FREQUENCY
INTENSITY
[Hz]
[PPM]
1
7837.7
21036.311 167.2763
0.45
2
10021.3
18858.576
149.9594
0.59
3
10666.1

39.8337
5.33
11
23917.6
4999.755
39.7570
0.79
12
23929.0
4988.411 39.6668 10.65
13
23938.8
4978.617 39.5889
0.80
14
23950.0
4967.418
39.4999 12.50
15
23971.1
4946.422
39.3329 10.63
16
23992.1
4925.430
39.1660 5.32
17
24013.2
4904.450
38.9992

INTENSITY
[Hz]
[PPM]
1
13318.1
15323.309 121.8477
6.25
2
14046.2
14656.019
116.5416
5.76
3
14241.9
14476.699
115.115 7
6.50
4
24582.6
5000.012
39.7590
1.26
KINH-HM1-DMSO-C13CPD
cr> VD
IT)
CM
a \
00
•
•

AQ
RG
DW
DE
TE
D1
dll
DELTA
MCREST
MCWRK
NUCl
PI
PLl
SFOl
CPDPRG2
NUC2
PCPD2
PL2
PL12
PL13
SF02
20070516
11.19
av500
5 mm Multinucl
zgpg30
65536
CDC13
256
2

LB
GB
PC
32768
125.7578513 MHz
EM
0
1.00 Hz
0
1.00
200
180 160
140 120 100
80
60 40
20
0 ppm
KINH-HM1-DMS0-C13CPD
VD
r'
CNJ
r-
cr>
uo
ơ^
VO
00
CNJ CNJ
o lO
rH

DW
15.300 usee
DE 6.00 usee
TE 303.1 K
D1 2.00000000 sec
dll
0.03000000 sec
DELTA 1.89999998 sec
MCREST
0.00000000 sec
MCWRK 0.01500000 sec
NUCl
13C
PI
8.60 usee
PLl -1.00 dB
SFOl
125.7703643 MHz
========
= CHANNEL f2 ========
CPDPRG2 waltzl6
NUC2
IH
PCPD2 88.00 usee
PL2 -3.00 dB
PL12
15.47 dB
PL13 22.00 dB
SF02
500.1320005 MHz

70 60
■ ' I • •
50
‘ M ^ ^ " I "
40 30
20
ppm
DEPT135
CH&CH3
CH2
90 80
-r.rp^
70
T^-p-r
60
200
190 180
170 160 150 140
130 120
110 100
• ■ I ”
50
■ ■ I ■ ■
40
■ ■ I ■ ■
30
' ' 1 ■ ■
20
ppm
KINH-HM1-DMS0-C13CPD&DEPT

#
ADDRESS
FREQUENCY
INTENSITY
[Hz] [PPM]
1
7837.7
21036.311
167.2763
0.45
2
10021.3
18858.576 149.9594
0.59
3
10666.1
18215.510
144.8459
0.72
4
13566.7
15322.783
121.8435
0.78
5
13586.8
15302.729
121.6841
0.45
6

10.65
13
23938.8
4978.617 39.5889
0.80
14
23950.0
4967.418 39.4999 12.50
15
23971.1
4946.422
39.3329 10.63
16
23992.1
4925.430 39.1660 5.32
17
24013.2
4904.450
38.9992
1.78
DU=C;/Bruker/XWIN-NMR, USER=VH_KINH, NAME=KINH_HM1, EXPN0=3, PR0CN0=1
Fl=215.OOOppm, F2=-5.OOOppm, MI=0.00cm, MAXI=10000.00cm, PC=1.400
#
ADDRESS FREQUENCY
INTENSITY
[Hz]
[PPM]
1
13318.1
15323.272

3
14241.9
14476.699 115.1157
6.50
4
24582.6
5000.012
39.7590
1.26
KINH-HMl-DMSO-IH
oo'^co^CNir-oro
rorocTk(T>oor^cr»c^
rorocMCNicMCNir'r^
r'r-r'r'r'r'VD<x>
ro
VD
<D
LT)
00 ro cn CM (T>
IT) iH o o o cr>
m LO m LO IT) ^
ro CM CM CM CNJ CvJ
14
13 12
11
10
8
k A
r-*
K D

MCWRK
NUCl
PI
PLl
SFOl
20070516
11.33
av500
5 mm Multinucl
zgSO
65536
DMSO
16
0
10000.000 Hz
0.152588 Hz
3.2769001 sec
161.3
50.000 usee
6.00 usee
302.7 K
1.00000000 sec
0.00000000 sec
0.01500000 sec
CHANNEL fl ========
IH
10.50 usee
-3.00 dB
500.1335009 MHz
F2 - Processing parameters

DS 0
SWH 10000.000 Hz
FIDRES 0.152588 Hz
AQ 3.2769001 sec
RG 161.3
DW 50.000 usee
DE 6.00 usee
TE 302.7 K
D1 1.00000000 sec
MCREST 0.00000000 sec
MCWRK 0.01500000 sec
=====
==== CHANNEL fl ========
NUCl IH
PI 10.50 usee
PLl
-3.00 dB
SFOl
500.1335009 MHz
F2 - Processing parameters
SI 32768
SF 500.1300027 MHz
WDW
EM
SSB
0
LB 0.30 Hz
GB
0
PC 1.00

15827.2
3668.122 7.3343
10.23
3
15886.8
3649.938
7.2980 5.23
4
15893.5
3647.904 7.2939
4.30
5
15913.8
3641.716 7.2815
5.51
6
15920.4
3639.681
7.2775 4.76
7
16719.6
3395.781 6.7898 8.81
8
16746.6
3387.555
6.7733 8.45
9
18566.9
2832.035
5.6626

CD ro Cr> VD CM CTN
LO rH O O O CT»
ro LO LT) IT) LO
ro CM CM CM CM CM
w
Current Data Parameters
NAME KINH_HM1
EXPNO 1
PROCNO 1
F2 - Acquisition Parameters
Date_ 20070516
Time 11.33
INSTRUM av500
PROBHD 5 m m Multinucl
PULPROG zg30
TD 65536
SOLVENT DMSO
NS 16
DS 0
SWH 10000.000 Hz
FIDRES 0.152588 Hz
AQ 3.2769001 sec
RG 161.3
DW 50.000 usee
DE 6.00 usee
TE 302.7 K
D1 1.00000000 sec
MCREST 0.00000000 see
MCWRK 0.01500000 sec
12

GB 0
PC 1.00
0 ppm
KINH-HMl-DMSO-lH
OD ^
ro CO
cn ro
TO ^ r-
0 0
CM CNJ CM CM
o CO
ơ\
r- r- r- r- r- r-
u
j
""“T^
7.4 7.3
7.2
7.1
7.0 6.9 6.8
k.
o
r-
o
CO
o
o
•
•
rH

DW 50.000 usee
DE 6.00 usee
TE
302.7
K
D1
1.00000000 sec
MCREST 0.00000000 sec
MCWRK
0.01500000 sec
= CHANNEL fl ====
= = = = =
NUCl
IH
PI
10.50 usee
PLl -3.00
dB
SFOl
500.1335009
MHz
F2 - Processing parameters
SI 32768
SF
500.1300027
MHz
WDW EM
SSB 0
LB
0.30 Hz